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Pesticide Storage and Disposal Safety02-01-01 | 16
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University of Arizona, College of Agriculture

The storage and disposal of pesticides and their empty containers are essential parts of pesticide use. A properly designed and maintained pesticide storage facility serves several important purposes, the most critical of which is protecting workers, visitors and animals from accidental contact with pesticides.

A pesticide storage facility also protects pesticides from temperature extremes, unauthorized use and theft. Because some urban and agricultural pesticides are more toxic and formulated in higher concentrations, keeping unqualified and/or inexperienced people out of the storage area is essential. The size of the storage facility you require will be dictated by the volumes and types of pesticides you use, as well as the types of containers you use.

Storage Facility Placement

According to Kenneth Davis, Compliance Projects Manager with the Arizona Department of Agriculture, it is a fine of $500 for every container that is not stored properly. The left items should have been placed on a shelf or a pallet.

The first step in planning a storage facility should be to contact government agencies to determine city/county zoning and building codes. Make sure you contact the local fire department for information regarding fire codes and/or ordinances relating to pesticide storage.

When planning a storage area, consider the slope of the area where the storage facility will be located. Select a site with as little slope as possible in order to prevent runoff and contamination of water supplies in the event of an accident or spill. It is also desirable to elevate the storage building at least 12 inches above the immediate ground level to prevent problems with moisture. Be aware of the possibility of flooding in extreme rain or storm events.

Legally, you are required to keep your storage facility at least 100 feet from wells. This is also the recommended distance for storage facilities from irrigation ditches, surface water, animal feed areas or shelters, and dwellings. If possible, consider the prevailing winds and think about what will lie downwind of your proposed site. Another consideration in location is easy access to vehicles for unloading and loading of pesticide material.

The Physical Structure

Liquid pesticides should be stored below or separately from dry pesticides. The containers are cracked, the contents of the container should be removed immediately and put into a new container.

Some pesticide storage buildings were originally built for other uses and may not have the proper specifications for storing pesticides. Changes can usually be made in nearly all these structures that will conform to the law and increase safety. Obvious first steps are changing or repairing doors so buildings or rooms can be surely locked. Post warning and identification signs.

The storage facility should allow for the separation of dry and liquid pesticide formulations. Herbicides are also separated from other pesticides to minimize cross-contamination. The ventilation system places the outlet away from the door so that any vapors will be drawn away from those entering the area.

The photo to the left shows bags of dry material everywhere except where they should be, which is on the empty pallet. The pallets at the top of the picture also look to be in a hazardous position.

Switch boxes, equipment storage, showers, emergency signals, and the eyewash station are located outside of the facility. The outside controls allow the fans and lights to be turned on before entering the structure. Outside storage of the fire extinguisher, personal protective equipment (PPE), and other items prevents contamination and allows ease of access.

A cooling system can be placed through a wall or on the ground. If possible, do not place such systems on the roof. This minimizes chances of a leaking cooling system contaminating stored material. A cooling system is desirable because chemicals subjected to high temperatures can expand, causing drum heads to bulge and leak.

High temperatures may also reduce effectiveness of emulsifiers, speed up container erosion and , in some cases, cause the pesticide to deteriorate. Low temperatures can cause compounds to settle or crystallize out of solution. Some compounds will freeze and upon expansion, rupture metal or glass containers.

The picture to the left violates one of the most important rules in chemical, pesticide, and fertilizer storage and that is to use "common sense."

When considering a new structure, remember that metal buildings are superior to frame construction because they afford ease in spill cleanup and increase safety in relation to a fire hazard. A concrete floor with a smooth finish is more desirable than a wood floor because the concrete can provide a curb for spill containment and there is less danger of chemical absorption. The smooth finish allows easier decontamination and increases resistance to chemical action. The floor should slope to a floor drain connected to a containment tank; do not allow drainage to municipal water supplies or the environment.

Whether you build a pesticide storage facility or modify an existing structure, the following items summarize steps to increase the safety and utility of the storage building:

- Use the facility for pesticide storage and handling only

- A fence that cannot be climbed, with a locked gate, should surround the storage building.

- Identification signs in English and Spanish, visible from any approach to the building, should be on the fence, on the building, and at each gate, door or window. Signs legible at 50 feet stating "CAUTION -- Hazardous Pesticide Storage Area -- Unauthorized Persons Keep Out," identify the area for the public and fire fighters.

-The storage area must be child proof.

-Install good lighting. Smoke and fire detection alarms, connected to an outside signal, are designed to warn of problems inside the locked building.

-The storage area should be isolated from other structures/work areas, not subject to flooding, and away from water supplies and public roads.

-Metal shelving with a lip for small pesticide container storage and metal racks for drum storage are easier to decontaminate than wood in the event of a spill. If necessary, use leak-proof plastic containers with a lip on non-metal shelving.

-Keep the storage facility well ventilated by passive or electric ventilation systems. Locate the intake and outlet vents at opposite ends of the building to facilitate air flow; if the outlet vent is away from the door, it moves vapors away from those entering.

-Post "NO SMOKING" signs. Do not allow smoking in the storage area.

-Install a telephone or indicate the location of the nearest telephone. Put emergency numbers by the phone, including Poison Control.

-Comply with ALL label storage requirements.

- Make an inventory of all pesticides available in storage and mark containers with the date of purchase.

- Keep copies of your storage inventory in the storage area and on file, and keep MSDS information in an accessible location.

Pesticide Storage

The picture is a real trouble spot. Both dry and liquid materials are stored with one another and piled into one big mess. The bottles in the front look to have a leak somewhere, and should be replaced.

Five gallon cans, metal drums, and cardboard cartons containing metal, glass, plastic, or paper packages are the most common types of stored pesticide containers. All pesticides should be stored in their original labeled containers and, if labels become illegible, obtain and attach replacement labels from your dealer or chemical sales representative. Only labeled original containers can legally be kept in storage. Consider covering your labels with transparent tape or lacquer to preserve them. Storage of clean packages that do not have pesticide residues lessens the danger of skin contact; inspect packages when you buy them and during use or handling for leaks and broken seals.

PPE, Leaks, Broken Packages, and Spills

Personal protective equipment (PPE) needed to prevent accidental contact depends on the product and its toxicity class. However, you must at least wear protective equipment for the skin, eyes, and lungs when handling packages that have been opened or are broken, leaking, or contaminated by a spill. The label on the product will list the protective clothing you need. Investing in a cleanup kit is a good idea. The kit should contain everything needed for a small spill cleanup: chalk, broom, mop, shovel, buckets, absorbent materials, sweeping compound, disposable protective clothing, gloves, boots, face shield or goggles, respirator or mask, and decontamination solution ingredients.

These photo showes the proper way of storing chemicals, pesticides, and fertilizers. Everything is up off the floor and on pallets. These materials are also on opposite sides of the storage facility and that will keep them from interacting with one another if the items in the pictures were to leak and mix with the another one. Also, the organization shown in both photos makes identifying materials easier.

"DANGER," "POISON," or skull and crossbones on the label are the signal words and symbols used on the most toxic pesticides. Product labels with the signal word "WARNING" are for intermediate toxicity compounds, and "CAUTION" indicates low toxicity compounds. WPS labels instructions specify PPE for handlers and mixer-loaders. General instructions such as "avoid skin contact," "keep from breathing dust or fumes," "wash hands and face after handling" and "keep out of eyes" imply that protective clothing and equipment are needed to reduce contact risk.

To prevent contamination from leaks of liquid pesticides, they should be stored below or separately from dry pesticides. Containers that have been opened and the contents used or partially used up, and containers that are leaking because of mechanical injury, corrosion, temperature extremes, and chemical breakdown are considered broken package storage. You can position leaking containers to temporarily stop a leak. Turn up or rotate a can or drum that has been punctured, putting the hole on top, to stop the contents from escaping. Use caution, as a metal container that has rusted and is leaking through a rusted-out spot must be handled carefully; the entire container may be weak and may collapse if handled roughly.

When you find a leak, immediately move the containers that have not been contaminated out of the area. This allows room to work and prevents clean containers from becoming contaminated. Stop the leak and confine the spill with an absorbent material. Transfer the contents of the leaking container to a new container or one that originally held the same material. Be certain the new container is properly labeled. Use the label cleanup procedures recommended for the particular product spilled or consult MSDS for expanded clean-up information.

General procedures for a dry spill cleanup include outlining the spill area with chalk or crayon. If the spill is within a marked area, you can tell if you are confining the spill. Put absorbing compound on a dry spill and sweep to the center of the spill area. Shovel up the residue and continue sweeping with more sweeping compound until the spilled material is removed. You can then use a decontamination solution recommended by the manufacturer of the product. Some decontamination solutions you might use are: full strength household bleach, hot soapy water, lye solutions, and solvents. Check the label or MSDS for specific instructions.

The illustration to the right shows an example of an ideal pesticide and chemical storage facility. Notice that dry and liquid materials are separated and off of the floor, and a ventilation fan is in place. Also, notice that a shower, eye wash station and locked personal protective equipment closet are not a part of the main storage area.

The curb at the front of the storage area will help spillage when loading and unloading materials into and out of the storage facility. The smooth concrete floor will aid in the clean up of any spills, and with all other chemicals and pesticides off the ground, dangerous materials will not interact with one another.

Always wear protective clothing, including eye and respiratory protection, when cleaning a spill or using a decontamination solution. Lye is a strong caustic and can burn skin, eyes or lungs, so handle decontamination solution with caution.

A liquid spill also should be outlined with chalk or crayon and the liquid soaked up with an absorbent material. You can use sawdust, industrial absorbent, cat litter, or even dry soil to surround and soak up the liquid spill. Sweep the absorbed material that has been saturated with the spilled liquid toward the center of the spill to avoid increasing the contaminated floor space. Shovel up and repeat until visible residues are removed. Decontaminate the area with decontamination solutions and rinse it with clean water.

Dispose of mop heads and any other cleaning equipment that cannot be decontaminated. The sweepings, decontamination solution, and rinse water must all be disposed of according to label instructions. It may be possible to apply the material to a labeled site; check with the Department of Agriculture. The companies that manufacture the pesticides you have in storage can supply you with specific cleanup and decontamination procedures for spills, and it is a good idea to have the information on hand so you can handle an emergency situation without delay.

Use the contents which might be contaminated from a spill first. That way they are the first to be disposed of and eliminated from the storage facility. First clean the outer surfaces. If the contents are contaminated, dispose of the pesticide. When handling contaminated containers, follow instructions regarding protective clothing.

Disposal Methods

It is the pesticide user's responsibility to see that unused chemicals and empty containers are disposed of properly. If you cannot use all of a pesticide material, the goal is permanent disposal as soon as possible. Using the storage facility as a temporary disposal site until you arrange permanent disposal has disadvantages because, if containers begin to leak, they can contaminate clean containers and the storage facility itself. In addition, the occupied storage area may be needed for storage of new pesticides. Temporary disposal in the storage facility may also take up space necessary for safe operation.

You can dispose of pesticides permanently in several ways. The most desirable approach is to avoid leftover pesticide by ordering and using only what you need. That way, pesticide storage and disposal are kept to a minimum. If that is not possible, deliver the material for burial at an approved sanitary landfill, if state and local regulations permit. Or, have a commercial solid waste disposal company collect the pesticides. You might also consider letting another qualified applicator use the material.

Disposal of empty pesticide containers is a continuing project for the applicator. In some cases, private applicators may produce empty containers almost daily during a crop season. One disposal option for these empty containers is recycling. Purchase pesticides in returnable containers whenever possible.

Triple rinsing is the first step in the disposal of a pesticide container. Triple rinsing steps are:

-Empty the pesticide container into the spray tank, letting it drain completely.

-Fill the container 1/4 to 1/5 full with water, close and shake the container vigorously so that all inside surfaces have been rinsed.

-Empty the rinse water into the spray tank, letting the container drain completely (at least 30 seconds).

-Repeat the rinsing procedure two more times, emptying the rinse water into the spray tank each time.

-Unless they can be returned to the manufacturer, all solid containers should be punctured and crushed so they cannot be reused.

A variety of products can aid in the clean up of spilled materials. A chemical spill kit, such as the one on the bottom right come with hazard gloves, polylaminated hood and boots, hazardous materials storage bag, sorbent pads and a warning sign.

It may be necessary to store empty containers short term because it is more economical to dispose of an accumulation of containers than to make daily trips to a landfill with a few. The main problems with temporary storage are the length of the storage period and the storage conditions. Empty containers must be stored with the same care as full containers. If the storage area becomes crowded with both empty and full containers, it may be tempting to dispose of the empty containers by putting them outside or disposing of them improperly.

If the storage area becomes crowded with both empty and full containers, it may be tempting to dispose of the empty containers by putting them outside or disposing of them improperly. If possible, set aside a certain area specifically devoted to storing the empty containers so they will not interfere with handling the full containers. Open-ended barrels are useful for storing these crushed containers.

Good lighting and readable labels make it much easier for landscape contractors to find what they are looking for as well as identify materials when there is a spill or a leak. All of the bottles shown in the above picture are free from residue and are all capped. The boxed items in the back of the storage unit are all neatly stacked with labels that clearly identify what they are, facing front.

Remember that empty containers still contain pesticide residues. When handling empty containers, you must still follow the label recommendations concerning protective clothing needed to prevent contact.

When dealing with pesticide storage and container disposal, it is important to follow the label and the intent of the law. Containers that held pesticides cannot all be treated alike. The product label will help you identify the procedure you need to follow in order to legally and safely dispose of each pesticide container. You may have additional strategies that work in your particular situation. Use common sense and read the label. Remember: the label is the law! LCM

(Information obtained from: Storage and Disposal of Pesticide and Containers on the Farm; Science and Education Administration-extension, U.S.D.A.; Store Pesticides Safely, Robert Billinger, Pesticide Information Program Information Sheet, Clemson Extension, May, 1996; Safe Handling, Storage and Transportation of Pesticides, The Pennsylvania State University, College of Agriculture Extension Service; Arizona Farm*A*Syst Program, The University of Arizona Cooperative Extension, 1996.)
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